DETERMINATION OF HETEROATOMIC COMPOUNDS IN OILS BY GAS CHROMATOGRAPHY-MASS-SPECTROMETRY
Rubrics: FIRE AND INDUSTRIAL SAFETY
Authors:
1.
Forensic center Main Department of the Ministry of Internal Affairs of Russia in Saint-Petersburg and Leningradskaya distr
2.
Forensic center Main Department of the Ministry of Internal Affairs of Russia in Saint-Petersburg and Leningradskaya distr
3.
Saint-Petersburg university of State fire service of EMERCOM of Russia
Type:
Article
Pages:
from 30
to 34
Status:
Published
Received:
12.12.2013
Accepted:
20.12.2013
Published:
25.12.2013
Language:
Russian
Keywords:
identification, oils, chromatography-mass spectrometry, heteroatomic compounds, phenols, ketones, mercaptans
Abstract (English):
Distillate fractions boiling up to 350 0C were checked by the method of gas chromatography-mass-spectrometry in ten samples of a commercial mixture of West Siberian oils in which a total of 48 individual heteroatomic compounds were identified. Among identified in crude oil heteroatomic compounds there were 12 mercaptans paraffinic and naphthenic series, 16 phenols, 9 aliphatic alcohols and 11 ketones. It was shown that the majority of corrosive heteroatomic compounds were concentrated in the abovementioned heavy fuel oils.
Distillate fractions boiling up to 350 0C were checked by the method of gas chromatography-mass-spectrometry in ten samples of a commercial mixture of West Siberian oils in which a total of 48 individual heteroatomic compounds were identified. Among identified in crude oil heteroatomic compounds there were 12 mercaptans paraffinic and naphthenic series, 16 phenols, 9 aliphatic alcohols and 11 ketones. It was shown that the majority of corrosive heteroatomic compounds were concentrated in the abovementioned heavy fuel oils.
Keywords:
identification, oils, chromatography-mass spectrometry, heteroatomic compounds, phenols, ketones, mercaptans
identification, oils, chromatography-mass spectrometry, heteroatomic compounds, phenols, ketones, mercaptans
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