An analytical model and a method for calculating the oxidation of gases in a block automotive neutralizer are given. The method makes it possible to determine the boundary conditions of the physicochemical process, the effect of diffusion in the porous catalyst and its efficiency, the thermal effects of oxidation of carbon monoxide, hydrocarbons and soot. The model is the theoretical basis for predicting the fire dangerous operation of automotive neutralizers at low temperatures in the Arctic.
engine, neutralizer, gas oxidation, thermal effect, fire hazard, analytical model
1. Lozhkin V.N., Onischenko I.A., Lozhkina O.V. Raschetnoe issledovanie pozharoopasnyh rezhimov raboty kataliticheskih neytralizatorov v usloviyah Arktiki // Nauch.-analit. zhurn. «Vestnik S.-Peterb. un-ta GPS MChS Rossii». 2016. № 3. S. 7-16.
2. Lozhkin V.N., Onischenko I.A., Lozhkina O.V. O modelirovanii himicheskoy kinetiki na makro i nano urovnyah v zadachah neytralizacii otrabotavshih gazov avtotransporta // Prirodnye i tehnogennye riski (fiziko-matematicheskie i prikladnye aspekty). 2016. № 3 (19). S. 30-34.
3. Frank-Kameneckiy D.A. Diffuziya i teploperedacha v himicheskoy kinetike. M.: Nauka, 1987. 502 s.
4. Boreskov G.K. Geterogennyy kataliz. M.: Nauka, 1986. 304 s.
5. Lozhkin V.N., Lozhkina O.V. Model for device for storage of excess heat and for neutralization of exhaust gases of fire trucks used in Arctic zone // Pozharovzryvobezopasnost - Fire and Explosion Safety. 2016. V. 25. pp. 84-91.
6. Pomerancev V.V., Aref'ev K.M., Ahmedov D.B. Osnovy prakticheskoy teorii goreniya: ucheb. posobie dlya vuzov / pod red. V.V. Pomeranceva. 2-e izd., pererab. i dop. L.: Energoatomizdat. Leningrad. otd-nie, 1986. 312 s.