THE SECOND PHASE DEVELOPMENT OF EXPERIMENTAL METHODS FOR DETERMINING FLASH POINT. PART 1
Abstract and keywords
Abstract (English):
The second stage of development of experimental methods for determination of flash and fire point covers the period from the 1920s to the 1980s. At the beginning of the last century, the most advanced devices and techniques for determining the flash point were already selected and legalized. There are the Abel, Abel-Pensky, Pensky-Martens Granier, Lushaire, Tag, Cleveland, Brenken, Marcusson and Treumann apparatuses. However, old naphtometers are used unofficially until the 30s of the 20th century. National standards on methods of determination of flash and fire temperature are emerging and being improved in phase II. By evolution, all the variety of instruments for determining the rate of flash and ignition (open, semi-closed and closed, open, semi-closed and closed steam apparatus, distillation testers) are reduced to two types of open and closed cups. But new methods (equilibrium, set-flash and continuous flow) and various designs of manual, semi-automatic and automatic instruments are emerging. The accumulated stock of experimental data for flash and fire point of liquids is reflected in the handbooks, which are used for fire safety. In the 60s–70s of the 20th century, a boundary is established between the flash point and the lower temperature flammability limit (lower flash point). Semi-closed type devices are considered.

Keywords:
flash point, fire point, device, apparatus, tester, naphtometer
Text
Text (PDF): Read Download
References

1. Bal N. Forty years of material flammability: An appraisal of its role, its experimental determination and its modelling // Fire Safety Journal. 2018. Vol. 96. P. 46–58. DOI:https://doi.org/10.1016/j.firesaf.2017.11.012.

2. Evolution of the classification of flammable and combustible liquids in Russia / S. Alexeev [et al] // Process Safety Progress. 2018. Vol. 37. № 2. P. 230–236. DOI:https://doi.org/10.1002/prs.11949.

3. Alekseev S.G., Smirnov V.V., Barbin N.M. Evolyuciya ponyatiya «temperatura vspyshki» // Tekhnosfernaya bezopasnost'. 2016. № 4 (13). S. 35–53. EDN: https://elibrary.ru/XROIXJ.

4. Alekseev S.G., Alekseev K.S., Barbin N.M. O temperature vspyshke organicheskih soedinenij // Bezopasnost' truda v promyshlennosti. 2018. № 11. S. 41–44. DOI:https://doi.org/10.24000/0409-2961-2018-11-41-44.

5. On the volatility and inflammability which fish and other fixed oils acquire by continued exposure to certain high temperatures / H. Wilson [et al] // The London Journal of Arts and Sciences. 1820. Vol. 1. № 3. P. 188–198.

6. Shah R., Streiber W. Determination of flash point instrumentation based on application // PIN. 2023. P. 8–10.

7. Yiin K.-C. Development of small scale liquid ignition test: dis. … doctor of philosophy. University of Oklahoma, 1979. 181 p.

8. Alexeev S.G., Smirnov V.V., Barbin N.M. First naphthometers to determine the flash point of liquids: II. Semislosed testers // Russian Journal of General Chemistry. 2021. Vol. 91. № 3. P. 508–519. DOI:https://doi.org/10.1134/S1070363221030191.

9. Alekseev S.G., Smirnov V.V., Barbin N.M. Istoriya klassifikacii legkovosplamenyayushchihsya i goryuchih zhidkostej v SSHA // Voprosy istorii estestvoznaniya i tekhniki. 2018. T. 39. № 3. S. 508–519. DOI:https://doi.org/10.31857/S020596060001121-5.

10. Alexeev S.G., Smirnov V.V., Barbin N.M. First naphthometers to determine the flash point of liquids: I. Open cup devices // Russian Journal of General Chemistry. 2021. Vol. 91. № 3. P. 495–507. DOI:https://doi.org/10.1134/S107036322103018X.

11. First naphthometers to determine the flash point of liquids: III. Vapor testers / S.G. Alexeev [et al] // Russian Journal of General Chemistry. 2021. Vol. 91. № 6. P. 1157–1170. DOI:https://doi.org/10.1134/S1070363221060281.

12. First naphthometers to determine the flash point of liquids: IV. Closed and distillation testers / S.G. Alexeev [et al] // Russian Journal of General Chemistry. 2021. Vol. 91. № 6. P. 1178–1189. DOI:https://doi.org/10.1134/S107036322106030X.

13. Alekseev S.G., Smirnov V.V., Barbin N.M. Ekspertiza vyskazyvaniya D.I. Mendeleeva o britanskom limite dlya bezopasnogo kerosina // Rossijskij himicheskij zhurnal. 2020. T. 64. № 1. S. 113–121. DOI:https://doi.org/10.6060/rcj.2020641.11.

14. Alekseev S.G., Smirnov V.V., Barbin N.M. Rozhdenie nemeckoj klassifikacii goryuchih zhidkostej i pervye testery temperatury vspyshki v Germanii // Istoriya i pedagogika estestvoznaniya. 2019. № 1. S. 45–51. DOI:https://doi.org/10.24411/2226-2296-2019-10109.

15. Evolyuciya metoda opredeleniya temperatur vspyshki i vosplameneniya v otkrytom pribore Klivlenda / S.G. Alekseev [i dr.] // Rossijskij himicheskij zhurnal. 2025. T. 69. № 2. S. 129–155. DOI:https://doi.org/10.6060/rcj.2025692.15.

16. Evolyuciya idej ognennyh testov kachestva kerosina / S.G. Alekseev [i dr.] // Bezopasnost' truda v promyshlennosti. 2020. № 9. S. 30–35. DOI:https://doi.org/10.24000/0409-2961-2020-9-30-35.

17. ASTM D 28-T. Tentative Test for Flash Point of Paint Thinners Other Than Turpentine // Proc. Twenty-First Annual Meeting. Atlantic City: ASTM, 1918. P. 685–688.

18. Redwood B. Petroleum. London: Charles Griffin & Co., Ltd, 1922. Vol. 3. 634 p.

19. Chamberlain C.D. Uniform oil inspection from a legal point of view. Eighth International Congress of Applied Chemistry. Section Vc «Fuels and Asphalt». Concord: The Rumford Press, 1912. Vol. 10. P. 91–101.

20. Alekseev S.G., Smirnov V.V., Barbin N.M. Istoriya vozniknoveniya klassifikacii legkovosplamenyayushchihsya i goryuchih zhidkostej v Velikobritanii // Istoriya nauki i tekhniki. 2017. № 12. S. 60–66. EDN: https://elibrary.ru/ZXLUQT.

21. White W. The Practice of Flash Point Determination: A Laboratory Resource / by ed. R.G. Montemayor. West Conshohocken: ASTM, 2013. 91 p.

22. Vlachos W., Vlachos C.A. The Fire and Explosion Hazards of Commercial Oils. Vlachos & Co., 1921. 292 p.

23. Battle J.R. The Handbook of Industrial Oil Engineering. Philadelphia, London: J.B. Lippincott Co., 1920. 1296 p.

24. Non-Standard devices for determination of temperature flammability limits / S.G. Alexeev [et al] // Russian Journal of General Chemistry. 2021. Vol. 91. Suppl. 1. P. S1–S12. DOI:https://doi.org/10.1134/S1070363221130326.

25. Ferraud J. Principes et Pratique des Essais Physiques et Chimiques Effectués sur les Produits Pétrolifère. Paris & Liège: Librarie Polytechnique Ch. Béranger, 1937. P. 127–142.

26. Bourgon L. Cours de Chimie Industrielle. Montrél: Imp. De l’École Technique de Montrél, 1930. № 3. P. 161.

27. Petroleum Testing Instruments. Linlot: Normalab Analis, 2007. 118 p.

28. Compendium of Environmental Laws of African Countries. Volume VIII: Sectoral Environmental Laws and Regulations. Nairobi: UNEP, 1998. P. ix, 87.

29. Appendice A 3. Epreuves relatives aux matières liquides inflammables des classes III a et IV a Memorial // Journal Officiel du Grand-Duché de Luxembourg. 1970. A–N 30. P. 697.

30. Ustrojstvo dlya opredeleniya temperatury vspyshki goryuchih zhidkostej v srede oksidov azota: A.S. 1402897 SSSR; MPK 4G01N25/52; zayavl. 24.04.1986; opubl. 15.06.1988 / Korolev V.M., Shchurin V.N., Mihalycheva E.A. 1988. № 22.

Login or Create
* Forgot password?